There's no nonstop path from Rhode Island to the Ionian, which means the real art of booking business class from Providence to Zakynthos lies in choosing the right connection, not just the right seat. Given that PVD's transatlantic options are limited, most seasoned travelers route through New York's JFK or Boston before heading overseas. From there, the strongest play is Lufthansa via Frankfurt or Munich, with a same-day or next-morning connection into Athens on a mainline aircraft, followed by an Aegean Airlines hop to Zakynthos, since ZTH itself only receives seasonal European short-haul service and cannot accommodate widebody aircraft. Lufthansa's long-haul business class product varies by aircraft, but on their 747-8 and A350 fleet you'll find fully flat seats with direct aisle access on many configurations, part of the airline's ongoing Allegris rollout on select routes. British Airways is another viable option, connecting through London Heathrow with its Club Suite on 777 and A350 aircraft, offering a proper door and genuine privacy that's become the benchmark for transatlantic business class comfort.
Athens is the real hinge point on this journey, and it deserves more attention than travelers usually give it. I always recommend building in at least a three-hour buffer there, since immigration lines for non-Schengen arrivals can be unpredictable in peak summer, and the walk between the international arrivals hall and the domestic Aegean gates is longer than it appears on paper. Aegean's short domestic hop to Zakynthos runs seasonally, generally from spring through autumn, so April, May, September and October aren't just the best months for fares — they're also when the connecting flight itself is most reliably scheduled, before the July-August crowds descend on the island.
Because this itinerary depends on stitching together three separate carriers, pricing swings more than most transatlantic routes, and the smartest travelers I know don't chase a single fare sale — they set continuous alerts across A3, LH, and BA routings so they can pounce the moment a favorable combination surfaces.