There's no nonstop path connecting Dulles to Alicante's compact terminal, and that's precisely what makes routing decisions the most important part of this trip. Business class from Washington Dulles to Alicante always requires a connection, and the three carriers worth your attention—Iberia, British Airways, and Lufthansa—each offer a genuinely different experience depending on your priorities for the roughly 8.5 hours of total flight time. My preferred routing runs through Madrid on Iberia, whose A330 and A350 business cabins feature fully lie-flat seats with direct aisle access on the A350, making the onward hop to Alicante feel like a formality rather than an ordeal. Iberia's Madrid hub also has the advantage of Spanish-speaking ground staff who can rebook you painlessly if Atlantic weather disrupts your connection, which happens more often than airlines like to admit in winter months.
British Airways routes through London Heathrow, and while the Club Suite on their 777s and A350s delivers excellent privacy with a sliding door, I've found the Heathrow connection can eat into your buffer time given Terminal 5's size—budget at least 90 minutes if you're transferring between long-haul and the short Iberia or BA CityFlyer hop onward. Lufthansa's option via Frankfurt or Munich brings their newer Allegris business seats into play on select aircraft, though as this product rolls out gradually, it's worth confirming your specific routing has been upgraded before booking on brand recognition alone. My insider tip: flying into Alicante rather than nearby Valencia or Barcelona saves considerable ground transfer time if your final destination is the Costa Blanca, since ALC sits just minutes from the coast.
April, May, September, and October consistently offer the best value on this corridor, as summer sees Spanish coastal demand spike and winter thins schedules considerably. Given how much these fares fluctuate by carrier and connection, setting up automated fare alerts for this specific city pair will save you from manually checking three airlines' shifting business class inventory.