Montpellier's modest regional airport handles no widebody long-haul traffic, which means there's no such thing as a true nonstop from Atlanta — every itinerary in business class from Atlanta to Montpellier routes through a major European or American hub, most reliably Paris-CDG via Delta or Air France, or Frankfurt/Munich via Lufthansa. In practice, Delta's daily ATL–CDG service, operated with their Delta One suites (sliding door on the A350 and A330-900neo), pairs beautifully with an Air France connection onward to Montpellier, since Delta and Air France share SkyTeam metal and often check bags straight through. Total journey time runs close to 13-14 hours door to door once you account for the short regional hop, but the transatlantic leg itself clocks in around 9.5 hours eastbound.
Having routed through CDG dozens of times on this connection, I always advise building in at least 90 minutes at Roissy — Terminal 2E, where Delta and Air France both operate, is sprawling, and the walk to regional gates can eat your buffer fast. Lufthansa's option through Frankfurt, using their new Allegris business class on select aircraft (though not guaranteed on this specific pairing yet, as rollout remains gradual), is worth checking if you're loyalty-aligned with Star Alliance, though the Munich routing sometimes offers a shorter regional connection into southern France. My insider tip: book the outbound leaving Atlanta on a Tuesday or Wednesday in shoulder season — Delta's revenue management tends to release saver business inventory earlier in the week when leisure demand to southern France softens.
January through March and October into November remain your best windows, both for award availability and softer cash fares, as Provence-adjacent Languedoc sees its tourist crush from May through September. Given how fluid pricing is on multi-carrier itineraries like this, setting up fare alerts specifically for the Atlanta–Montpellier corridor will save you from manually checking three airlines' inventory every week.